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Chapter 1: Measurement and Quantities
Chapter 1.3: Measured Numbers and Significant Figures
Exact & Inexact Numbers

Exact Numbers
A 2-Part Definition: 
(Remember both parts!)
.
1.
  Numbers obtained by counting items Ex:  1 potato
or
2.
  From an equality between two units 
  in the same measuring system Ex:  1 yd = 3 ft
.
Examples:
.
1.
  Exact Numbers are 8 doughnuts
  Numbers obtained by counting items 2 baseballs
or
2.
  Exact Numbers are
  From an equality between two units
  in the same measuring measuring system
.
U.S. System
1 foot is exactly 12 inches
1 quart is exactly 4 cups
or
Metric System
1 L = 1,000 mL
1m = 100 cm
.

  • The number one in any conversion is always an exact number, whether the units are in the same system or not.
Inexact Numbers a.k.a. Measured Numbers
The numbers you obtain when you use a measuring tool to determine height, weight or temperature.

Examples:
.
The statue is 10.525 meters in height.  It is 13.8 ºC outside.

Some measuring tools are more precise than others, enabling a more accurate reading
.
but no matter how precise a measurement is, the final digit in the measured number will always be an estimated digit.


Precision & Accuracy in Measurement

Precision
The degree to which individual measurements agree with one another.

Accuracy
The degree to which measurements taken agree with the correct or standard value.


 

  • If measuring tools are not calibrated properly, measurements can be precise but still be inaccurate.

  • Calibrating an instrument improves its accuracy.

    Example:  All the clocks in the house say exactly 3:15.  The time is precise.
                     But they are all inaccurate:  The actual time is only 3:00.



Error and Percent Error in Measurement

Some quantities have an
Accepted Value
The correct value based on reliable references.

Example:
  The accepted value for the boiling point of water is 100 ºC.

Experimental Value
The value measured in a lab

Example:
  You measure the boiling point of water at 99.1 ºC.

Error
The difference between the experimental value and the accepted value.

Example:

Error = experimental value – accepted value

Error = 99.1 ºC – 100 ºC = – 0.9 ºC

Percent Error a.k.a. Relative Error
The absolute value of the error divided by the accepted value, multiplied by 100%.

Example:
Percent Error =
       |error| 
accepted value 
x 100%
.
Percent Error =
    |– 0.9 ºC| 
100 ºC
x 100%   = 0.9%



Significant Figures

Significant Figures
the numbers recorded in a measurement, including the estimated digit

  • Exact numbers are not measured, do not have a limited number of significant figures, and do not affect the number of significant figures in a calculated answer.

  •  
  • Measurements must always be reported to the correct number of significant figures because calculated answers often depend on the number of significant figures in the values used in the calculation.
Examples:

     You measure the mass of an object to be 27.5 kg.

     Because it is a measurement, the number has significant figures.

     The measurement 27.5 kg has three (3) significant figures.

     All the numbers in the measurement are significant.

     However, in the measurement of 0.070 kg, only two (2) of the figures are significant.



How can we determine which numbers are significant and which are not?


Rules for Significant Figures
1.
A number IS a
significant figure
if it is...
Example:
Number of
significant figures
a)  not a zero
4.5 g
2
122.35 kg 
5
.
b)  a zero between nonzero digits
205 m
3
5.082 kg
4
.
c)  a zero at the end of a
     number with a decimal 
50. L
2
25.0 °C
3
16.00 g
4
.
d)  any digit in the coefficient
     of a number written in
     scientific notation
5.70 x 10-3 g
3
.
.
2. A zero IS NOT
a significant figure
if it is...
Example:
Number of
significant figures
a)  at the beginning
     of a decimal number
0.0004 lb
1
0.075
2
.
b)  used as a placeholder
     in a number without a decimal
850,000 m
2
1,250,000 g
3
.
Significant Figures do not apply to Exact Numbers.
Click HERE for a Significant Rules Handout!
.What is the difference between exact & measured numbers?
 
Practice Problems
Answer the following questions:
1. Identify each of the following numbers as measured or exact; give the number of significant figures in the measured numbers.
.
a) 42.2 g b) 3 eggs c) 5.0 x 10-3 cm
.
d) 450,000 km e) 8 pencils f) 1,000 g = 1 kg
2. For the following measured numbers, indicate if the zeroes are significant:
.
a) 300.09 L b) 2.0 g c) 0.000 95 m
.
d) 1,000 days e) 1.00 x 10–9 L f) 7.05 x 103 kg
3. State the number of significant figures in each of the following measurements:
.
a) 0.000 35 g b) 2,000 m c) 2.004 5 L
4. Can a measurement be both precise and inaccurate?  Explain.
5. A student experimentally determines the boiling point of water to be 98.6 ºC.

The actual boiling point of water is 100 ºC.

Calculate the error AND the percent error.

2 problems, 3 points each:
     1 point for setting up the problem correctly,
     1 point for the correct answer,
     1 point for the proper units and 6 points total!

Sources: CHEMISTRY - an Introduction to General, Organic, & Biological Chemistry, Prentice Hall CHEMISTRY, Modern CHEMISTRY, CHEMISTRY - the Central Science, and Principles & Applications of CHEMISTRY
Donaghe's Science
Donaghe's CHEMISTRY - Matter and Reactions
Unit One: Basic Principles
Chapter 1: Measurement and Quantities
Chapter 1.1: Units of Measurement
Chapter 1.2: Scientific Notation
Chapter 1.3: Measured Numbers and Significant Figures
Chapter 1.4: Significant Figures in Calculations
Chapter 1.5: Prefixes and Equalities
Standards, Objectives, and Vocabulary
 
Unit One: Basic Principles
Unit Two: Matter and Energy
Unit Three: Elements and Atoms
Unit Four: Compounds and Bonds
Unit Five: Reactions and Relationships
Cool Chemistry Videos
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Chapter 1.3:
Measured Numbers
& Significant Figures
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Chapter 1.2:
Scientific Notation