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Chapter 6: The Atom
Chapter 6.1: Atomic Structure
Atom
The smallest particle of an element that retains the characteristics of that element.

Democritus (460-370 BC)
believed all matter was made of atoms, which were indivisible & indestructible

John Dalton (1766-1844)
English chemist, physicist, & meteorologistalso an expert on color blindness (which he was)

Dalton’s Atomic Theory – 1808
1. All matter is made up of tiny particles called atoms.
2. All atoms of a given element are similar to one another and different from atoms of other elements.
3. Atoms of two or more different elements combine to form compounds:  A particular compound is always made up of the same kinds of atoms and always has the same number of each kind of atom.
4. A chemical reaction involves the rearrangement, separation or combination of atoms.  Atoms are never created or destroyed during a chemical reaction.

Dalton initially conceived of atoms as solid, indivisible spheres: "The Billiard Ball Model."
By the late 1800’s, scientists realized this was not the case.

Electrical Charges in an Atom

Atoms are composed of smaller parts called
Subatomic particles.

Some subatomic particles have electrical charges.

Like charges repel.
Unlike charges attract.

Hair gets flyaway look when you take off a hat, leaving hair with positive charge
Clothes from the dryer stick together and have static electricity

 Structure of the Atom

1897 English Physicist J. J. Thompson
Discovered atoms contained both positive and negative charges 


cathode-ray tube experiment
electron e
a negatively-charged subatomic particle having a very small mass that orbits the nucleus in mostly empty space

proton p+
a positively-charged subatomic particle having a mass of 1 a.m.u. (atomic mass unit) and found in the very small, dense nucleus of an atom

Atoms are electrically neutral.
In a neutral atom, 

the number of protons equals the number of electrons.

1911 New Zealand Physicist Ernest Rutherford
atoms mostly empty space, protons contained in the nucleus 


gold foil experiment


Scientists
     knew mass of individual protons
     knew the mass of the nucleus

But the mass of the protons was not enough to account for the mass of the nucleus.
There had to be another particle inside the nucleus.

1932, British Physicist James Chadwick

polonium-beryllium experiment
neutron nº
a neutral subatomic particle having a mass of 1 a.m.u. and found in the nucleus of an atom

nucleus
the compact center of an atom, containing the protons and neutrons of the atom

Mass of the Atom
One proton has mass of 1.7 x 10–24 g

One electron has a mass 1/1840 of a hydrogen atom.

atomic mass unit (amu)
a small mass unit used to describe the mass of very small particles such as atoms and subatomic particles

1 amu = one-twelfth the mass of a C-12 atom (6 nº + 6 p+)

Relative Atomic Masses of the Subatomic Particles

Neutron = 1 a.m.u
Proton = 0.99862349 a.m.u.
Electron = 0.00054386734 a.m.u

Notice that the sum of the masses of the proton & electron is nearly 1 (0.999) and the sum of their charges is zero—same as a neutron!
 

Particle Charge Mass Location
proton, p+ positive, +1 0.999 a.m.u in the nucleus
neutron, nº none, 0 1.000 a.m.u.
electron, e negative, –1 5.44 x 10–4 amu orbiting the nucleus

What are the subatomic components of the atom?
 
Practice Problems
Answer the following questions:
1.  Are all atoms of a given element the same?

2.  Are there any atoms of one element that are identical to atoms of another element?

3.  Do atoms have an electrical charge?

4.  What are subatomic particles?
       Name one.

5.  Are there any subatomic particles with an electrical charge?
       Name one

6.  Does the nucleus of an atom have an electrical charge?
      If so, what is the charge and if not, why not?

7.  Which have more mass-- protons or electrons?

8.  Are protons electrically attracted to neutrons?

9.  Because they have so little mass, do they have electrical charge?

10.  Because they have the same charge, are electrons attracted to each other?

11.  Are all the protons and neutrons of an atom contained within the nucleus?

12.  Because the atom is electrically neutral, are there some electrons contained within
        the nucleus?

13.  How much of the volume of an atom is made up of the nucleus?
        How much of the mass of an atom is made up by the nucleus?
 

Sources: CHEMISTRY - an Introduction to General, Organic, & Biological Chemistry, Prentice Hall CHEMISTRY, Modern CHEMISTRY, CHEMISTRY - the Central Science, and Principles & Applications of CHEMISTRY
Donaghe's Science
Donaghe's CHEMISTRY - Matter and Reactions
Unit Three: Elements and Atoms
Chapter 6: The Atom
Chapter 6.1: Atomic Structure
Chapter 6.2: Atomic Number and Mass Number
Chapter 6.3: Isotopes and Mass Number
Standards, Objectives, and Vocabulary
 
Unit One: Basic Principles
Unit Two: Matter and Energy
Unit Three: Elements and Atoms
Unit Four: Compounds and Bonds
Unit Five: Reactions and Relationships
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Chapter 6:
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